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Visible Luminescence Centers In Zinc Oxide Films Deposited by Spray Pyrolysis

Publication Type : Journal Article

Source : Journal of Optoelectronics and Advanced Materials

Url : https://www.scopus.com/record/display.uri?eid=2-s2.0-38549112561&origin=resultslist&sort=plf-f

Campus : Amritapuri

School : School of Physical Sciences

Department : Physics

Year : 2007

Abstract : Zinc oxide (ZnO) films were deposited by spray pyrolysis. Photoluminescence (PL) and electrical resistance investigations on the samples revealed that oxygen vacancy is a deep donor and singly ionized state of oxygen vacancy (Vo+) is responsible for green luminescence from the samples. The shift observed in luminescence peak with substrate temperature has revealed the effect of local lattice relaxation and crystal imperfections on the visible luminescence of ZnO. The PL spectra of the sample annealed in air suggest that oxygen vacancies are the visible luminescent centers in ZnO and also predict that doubly ionized oxygen vacancy (Vo++) along with zinc vacancy (VZn) may be causing emission at ∼2.07 eV in annealed samples.

Cite this Research Publication : Visible luminescence centers in zinc oxide films deposited by spray pyrolysis Rakhesh, V., Junaid Bushiri, M., Vaidyan, V.K. Journal of Optoelectronics and Advanced Materials, 2007, 9(12), pp. 3740–3742

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