Back close

Synthesis, Characterization and liquid crystalline properties of 1,3-bis(4-pyridyl)propane connected long alkyl chain Dicobaloximes

Publication Type : Conference Proceedings

Publisher : Materials today proceedings

Source : Materials today proceedings, 5, 16748-16755. (I.F – 0.8)

Url : https://www.sciencedirect.com/science/article/abs/pii/S2214785318311465

Campus : Coimbatore

School : School of Physical Sciences

Year : 2018

Abstract : Synthesis, characterization and mesomorphic properties of dpyp-linked dicobaloxime of the kind [C15H31-CH2Co(dmgH)2]2-µ-1,3-bis(4-pyridyl)propane has been reported. This cobaloxime complex was characterized by UV-visible and Fourier Transform Infrared spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy. Thermal properties of the complex have been studied by thermo gravimetric and differential thermal analysis. A comparative study of the mesophase formation and thermal stability of the ligand bridged dicobaloxime with long alkyl chain complexes has been reported. Liquid crystalline properties of these complexes were observed by differential scanning calorimetry and polarizing optical mircroscopy. Liquid crystalline properties of these compounds profoundly depend on the axial alkyl chain length.

Cite this Research Publication : S. Sarath, R. Yamuna, () Synthesis, Characterization and liquid crystalline properties of 1,3-bis(4-pyridyl)propane connected long alkyl chain Dicobaloximes, Materials today proceedings, 5, 16748-16755. (I.F – 0.8)

Admissions Apply Now