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Synthesis and characterization of axially linked heteroleptic polymeric and monomeric lewis base adducts of BIS-(2-mercaptobenzothiazolato) Nickel(II) and its extraordinary thermal decomposition

Publication Type : Journal Article

Publisher : Asian Journal of Chemistry

Source : Asian Journal of Chemistry, vol. 25, pp. 7669-7674, 2013

Url : http://www.scopus.com/inward/record.url?eid=2-s2.0-84883335384&partnerID=40&md5=6ac3f97a62440f7a4aee8de7a2199ac3

Campus : Amritapuri

School : School of Arts and Sciences

Department : Chemistry

Year : 2013

Abstract : {Six coordinated axially bridged heteroleptic polymeric and monomeric Lewis base adducts from coordinatively unsaturated bis-(2-mercaptobenzothiazolato) nickel(II) {Ni(mbt)2, [NiC14H8N 2S4]} have been synthesized and charecterized by elemental analysis, spectral techniques, magnetic susceptibility measurements and thermal analysis using coordination sphere expansion method. These adducts have general molecular formula [Ni(mbt)2L]n for polymeric adducts and [Ni(mbt)2L2] for monomeric adducts, where L = pyrazine, 4,4′-bipyridine and 4,4′-azopyridine

Cite this Research Publication :
M. S. Suresh and Prof. M. Padmanabhan, “Synthesis and characterization of axially linked heteroleptic polymeric and monomeric lewis base adducts of BIS-(2-mercaptobenzothiazolato) Nickel(II) and its extraordinary thermal decomposition”, Asian Journal of Chemistry, vol. 25, pp. 7669-7674, 2013

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