Publication Type : Journal Article
Publisher : Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Source : Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 79, Number 5, p.1418 - 1424 (2011)
Url : http://www.sciencedirect.com/science/article/pii/S138614251100326X
Keywords : Tetranuclear
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2011
Abstract : Phenoxide bridged later first row transition metal(II) complexes have been prepared by the interaction of later 3d transition metal(II) chlorides with tetranucleating compartmental Schiff base ligand system derived from 2,6-diformyl-4-methylphenol, p-phenylenediamine and 2-hydrazinobenzothiazole. Ligand and complexes were characterized by analytical, spectral (IR, UV–visible, ESR, FAB-mass and fluorescence), magnetic and thermal studies. All complexes are found to have octahedral geometry. The mutual influence of metal centres in terms of cooperative effect on the electronic, magnetic, electrochemical and structural properties was investigated. The Schiff base and its complexes have been screened for their antibacterial (against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa) and antifungal activities (against Aspergillus niger, and Candida albicans).
Cite this Research Publication : Anupama Kamath, Dr. Naveen V. Kulkarni, Priya P. Netalkar, and Vidyanand K. Revankar, “Phenoxide bridged tetranuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes: Electrochemical, magnetic and antimicrobial studies”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 79, pp. 1418 - 1424, 2011.