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Performance evaluation of nickel as anode catalyst for DMFC in acidic and alkaline medium

Publication Type : Journal Article

Publisher : Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

Source : Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, Science Press, Volume 46, Number 5, p.592-599 (2018)

Url : https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053308469&partnerID=40&md5=c19cb96ebf49d6491c3f60d8ae7b9987

Keywords : Alkaline electrolytes, Catalyst activity, Catalytic behavior, Catalytic layers, Catalytic oxidation, Cyclic voltammetry, Direct methanol fuel cells (DMFC), Electrodes, Electrolytes, Electrooxidation, High energy densities, Maximum current density, Mesh generation, methanol, Methanol fuels, Methanol Oxidation, Nickel, oxidation, Performance evaluations, Platinum catalysts

Campus : Coimbatore

School : School of Engineering

Department : Sciences

Year : 2018

Abstract : Direct methanol fuel cell (DMFC) research is highly focused due to its high energy density, portability and inexpensive. In the present study conventional platinum catalyst used for methanol oxidation is being replaced with nickel catalyst supported over nickel mesh. The electrode is synthesized by single step electro deposition technique. Synthesized electrode was characterized by SEM, EDAX and AFM techniques to know the surface morphology, composition and thickness of the catalyst respectively. The electro catalytic behavior of the nickel for methanol oxidation was evaluated using cyclic voltammetry technique. As the DMFC is compatible with both the acidic and alkaline electrolytes the working of the nickel mesh electrode is analyzed in both media. The results showed maximum current density of 0.025 and 0.030 A/cm2 in alkaline and acidic medium respectively with less potential around 0.4 and 0.2 V. The other parameters such as varying the concentration of methanol, electrolyte medium, scan rate and thickness of the catalytic layer were analyzed and optimized. © 2018, Science Press. All right reserved.

Cite this Research Publication : M. Sunitha, Durgadevi, N., Dr. Asha Sathish, and T. Ramachandran, “Performance evaluation of nickel as anode catalyst for DMFC in acidic and alkaline medium”, Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, vol. 46, pp. 592-599, 2018.

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