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Organocobaloximes with mixed dioxime equatorial ligands: a convenient one-pot synthesis. X-ray crystal structures of BnCo III (dmgH)(dpgH) Py and BnCO III (chgH)(dpgH) py

Publication Type : Journal Article

Thematic Areas : Advanced Materials and Green Technologies

Publisher : Elsevier

Source : Journal of Organometallic Chemistry, Elsevier, Volume 627, Number 1, p.80–92 (2001)

Url : http://www.sciencedirect.com/science/article/pii/S0022328X01007318

Campus : Coimbatore

School : School of Engineering

Center : Center for Excellence in Advanced Materials and Green Technologies

Department : Chemistry, Civil, Sciences

Year : 2001

Abstract : A simple and general route to the synthesis of organocobaloxime with mixed dioxime ligands, RCo(dmgH)(dpgH)Py and RCo(chgH)(dpgH)Py, has been described. The 13C-NMR chemical shifts have been analysed to see whether one dioxime wing has any effect on the other dioxime wing. The first crystal structure of an organocobaloxime with mixed dioxime ligand in the same complex, BnCo(dmgH)(dpgH)Py and BnCo(chgH)(dpgH)Py, is reported.

Cite this Research Publication : B. D. Gupta, Dr. Yamuna R., Singh, V., Tiwari, U., Barclay, T., and Cordes, W., “Organocobaloximes with mixed dioxime equatorial ligands: a convenient one-pot synthesis. X-ray crystal structures of BnCo III (dmgH)(dpgH) Py and BnCO III (chgH)(dpgH) py”, Journal of Organometallic Chemistry, vol. 627, pp. 80–92, 2001.

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