Publication Type : Journal Article
Publisher : Inorganic Chemistry
Source : Inorganic Chemistry, Volume 51, Number 10, p.5605-5616 (2012)
Url : http://dx.doi.org/10.1021/ic202510d
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2012
Abstract : { A multicomponent synthetic strategy involving copper(II) ions, tert-butylphosphonic acid (t-BuPO3H2) and 3-substituted pyrazole ligands has been adopted for the synthesis of soluble molecular copper(II) phosphonates. The use of six different 3-substituted pyrazoles, 3-R-PzH [R = H, Me, CF3, Ph, 2-pyridyl (2-Py), and 2-methoxyphenyl (2-MeO-C6H4)] as ancillary ligands afforded nine different decanuclear cages, [Cu5(μ3-OH)2(O3P-t-Bu)3(3-R-Pz)2(X)2]2·(Y) where R = H
Cite this Research Publication : Vadapalli Chandrasekhar, Loganathan Nagarajan, Sakiat Hossain, Dr. Gopal K., Surajit Ghosh, and Sandeep Verma, “Multicomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages”, Inorganic Chemistry, vol. 51, pp. 5605-5616, 2012