Publication

Abstract : Mercury (Hg) contamination in aquatic systems is a universal concern because of its persistence, bioaccumulation, toxicity, and trans-boundary nature. The current study focuses on monitoring the fate and transport of Hg in aquatic matrices such as water, interstitial water, sediment and fish in a tropical coastal ecosystem. The cold vapour atomic fluorescence spectrometer was used for the Hg analysis. The study assessed the fractionation of Hg and its methylation potential in sediments. The high Hg concentration in fish tissues showed the ineffectiveness of biogeochemical control over the methyl Hg mobility and bioavailability through the food web. Research results indicate that the accumulation potential of Hg subsequently increases along the food chain. The conducive physico-chemical environment at the sediment–water interface supports chemical transformations/transport of Hg from one matrix to the next. The fate of Hg in the lake has also been discussed based on the data generated.