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Influence oF Zn/Sn stoichiometric ratio in solution processed zinc stannate microcubes for photodetector applications

Publication Type : Journal Article

Publisher : Springer

Source : J. Mater. Sci. Mater. Electron., 34 (2023)

Url : https://link.springer.com/article/10.1007/s10854-022-09519-5

Campus : Coimbatore

School : School of Engineering

Year : 2023

Abstract : Zn2SnO4 microcubes with interlocked morphology were synthesized using simple chemical precipitation technique using Zn(CH3COO)2·2H2O and SnCl4·5H2O as the reagents. The structural characterization using X-ray diffraction confirmed the formation of inverse spinel structure. The bandgap shift owing to Burstein–Moss shift and effect of Zn/Sn stoichiometry on luminescence property of the synthesized sample is discussed in detail. The additional SnO2 peaks obtained from Raman spectrum also confirm the influence of Zn/Sn stoichiometry. The mixed cubic-nanoplate morphology of nanoparticles was confirmed from FESEM analysis. The dielectric-dc conductivity studies of the sample confirmed the semiconducting nature and n-Zn2SnO4/p-Si junction diodes were fabricated which exhibited good photoresponse.

Cite this Research Publication : S.G. Kavya, M.S. Amrutha, L. Mohan, P. Kathirvel, S. Saravanakumar, Influence oF Zn/Sn stoichiometric ratio in solution processed zinc stannate microcubes for photodetector applications, J. Mater. Sci. Mater. Electron., 34 (2023)

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