Publication

Abstract : We evaluate the effects of rapidly changing Arctic sea ice conditions on sea salt aerosols (SSA) produced by oceanic wave-breaking and the sublimation of wind-lofted salty blowing snow on sea ice. We use the GEOS-Chem chemical transport model to assess the influence of changing extent of the open ocean, multi-year sea ice (MYI), first-year sea ice (FYI), and snow depths on SSA emissions for 1980–2017. We combine snow depths from the Lagrangian snow-evolution model (SnowModel-LG) together with an empirically-derived snow salinity function of snow depth to derive spatially and temporally varying snow surface salinity over Arctic FYI. We find that pan-Arctic SSA surface mass concentrations have increased by 6%–12% decade−1 during the cold season (November–April) and by 7%–11% decade−1 during the warm season (May–October). The cold season trend is due to increasing blowing snow SSA originating from FYI: as MYI is replaced by FYI with thinning snow depths, snow surface salinity increases by more than 11% decade−1. During the warm season, rapid sea ice loss and thus increasing open ocean SSA are the cause of modeled SSA trends. Observations of SSA mass concentrations at Alert, Canada display positive trends during the cold season (10%–12% decade−1), consistent with our pan-Arctic simulations. During fall, Alert observations show a negative trend (−18% decade−1), due to locally decreasing wind speeds and thus lower open ocean emissions. These significant changes in SSA concentrations could potentially affect past and future bromine explosions and Arctic climate feedbacks.