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Electrochemical and hot corrosion behaviour of steel reinforced with AlSiBeTiV high entropy alloy using friction stir processing

Publication Type : Journal Article

Publisher : Taylor and Francis Ltd.

Source : Science and Technology of Advanced Materials, 25(1)

Url : https://www.tandfonline.com/doi/full/10.1080/14686996.2024.2320083

Campus : Coimbatore

School : School of Engineering

Department : Mechanical

Year : 2024

Abstract : A lightweight AlSiBeTiV high entropy alloy (HEA) powder is synthesized by the ball milling process and is reinforced on SS410 through friction stir processing (FSP). Subsequently, the annealing process is conducted on the processed samples at 450, 600, and 750°C for 120 mins. The grains are refined at 600°C by 23.3% than the processed HEA sample. A higher microhardness of 672 HV is attained on the processed HEA sample annealed at 600°C due to the synergistic effect of FSP and annealing through refined grains. The electrochemical corrosion under a 3.5 wt.% NaCl environment, and the hot corrosion under the salt mixture environments of 75% Na2SO4 +25% NaCl, and 60% Na2SO4 +20% NaCl + 20% V2O5 at 800°C for 50 h are investigated on the processed samples. The microstructure, induced corrosion products, and elemental distribution of the corroded surface of the annealed processed HEA sample are evaluated by morphological analysis. The induced oxidation effect enhances the Cr2O3 and TiO2 films on the corroded surfaces leading to higher corrosion resistance. A high corrosion resistance appears on the annealed processed HEA sample through the formation of a stable passive layer, hindering the pitting corrosion mechanism, grain refinement, and homogeneous distribution.

Cite this Research Publication : Sundaram, R., Nachimuthu, R., Sivanandam, A. K., & Natarajan, J. (2024). Electrochemical and hot corrosion behaviour of steel reinforced with AlSiBeTiV high entropy alloy using friction stir processing. Science and Technology of Advanced Materials, 25(1). https://doi.org/10.1080/14686996.2024.2320083

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