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Asymmetric induction by (S)-4-isopropyl-1-phenylimidazolidin-2-thione in titanium mediated aldol reactions and its application in enantioselective synthesis of (R)-baclofen

Publication Type : Journal Article

Publisher : Thieme

Source : Synthesis, 2011

Url : https://thieme-connect.com/products/ejournals/abstract/10.1055/s-0030-1260187

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2011

Abstract : The usefulness of (S)-4-isopropyl-1-phenylimidazolidin-2-thione as a chiral auxiliary in stereoselective propionate and acetate aldol reactions is discussed. Further, the enantioselective synthesis of (R)-baclofen by acetate aldol reaction using the chiral auxiliary was demonstrated.

Cite this Research Publication : Gopal L. Khatik, Ravi Khurana, Varun Kumar and Vipin A. Nair, "Asymmetric induction by (S)-4-isopropyl-1-phenylimidazolidin-2-thione in titanium mediated aldol
reactions and its application in enantioselective synthesis of (R)-baclofen", Synthesis, 2011, 43, 3123-3132

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