Syllabus
Unit 1
Brief history of birth of quantum theory:
Classical and electrical nature of matter and atoms, electrons; Black-body radiation, Photons, photoelectric effect, dual nature of electromagnetic radiation.
Line spectra, Rutherford and Bohr models of hydrogen atom and atomic spectra, Franck-Hertz experiment, generalized Bohr-Sommerfeld quantization rules, energy levels of particle in a box and simple harmonic oscillator, correspondence principle; X-ray spectrum. [9]
Unit 2
Electron diffraction, de Broglie model, wave-particle duality, Schrodinger equation, probability amplitudes and probabilities, superposition of waves, group velocity, uncertainty relations, estimation zero-point energies of simple potentials. [5]
Schrödinger equation and its properties, wave functions, superposition, normalization, expectation values, momentum and energy operators; time-independent Schrodinger equation, stationary states, energy eigenvalue equation, eigenvalues, eigenstates and quantization of energies, infinite and finite potential wells. [6]
Unit 3
Simple harmonic oscillator, vibrational levels of diatomic molecules. [4] (Refs.2)
Free particles, wave packets, potential steps and barriers, reflection, transmission and tunnelling, resonant tunnelling, scanning tunnelling microscope. [5]
Particles in two- and three-dimensional rigid boxes, and simple harmonic potentials in Cartesian coordinates. [2]
Unit 4
Angular momentum and magnetic moment, Stern-Gerlach Experiment, angular momentum quantization, angular momentum operators, Azimuthal angular momentum eigenvalues and eigenstates; uncertainty relations with position, momentum, and angular momentum. [5] (Ref.2) Schrodinger equation in central fields, Total angular momentum eigenvalues and eigenfunctions – spherical harmonics, vector model, rotational quantum states of molecules. [4] (Ref.2)
Unit 5
Spin angular momentum – states and eigenvalues, spin magnetic moment, spin-orbit coupling energy, addition of Spin and angular momentum in the vector model, Zeeman effect. [4] (Ref.2)
Hydrogen atom: Schrodinger equation in spherical coordinates; radial solutions, complete set of wave functions, classification of energy eigenstates, spectroscopic notation. [4] (Ref.2)
Many electron atoms: Identical particles, permutation symmetry, two electron systems, symmetric and anti-symmetric wave functions and spin states, Pauli principle. [2] (Ref.2)
Qualitative discussions of states of helium and many electron atoms. [2] (Ref.2)
Summary
Description: This course introduces ideas in quantum physics at an elementary level and forms the foundation for more advanced courses.
Course Objectives and Outcomes
Course Outcomes:
On completion of this course, students shall be able to
- Describe phenomena of nature that differed from classical predictions; understand the phenomena origins of quantum nature of the physical world at the atomic scale
- Get introduced to Schrodinger theory of atomic phenomena and perform basic calculations and correlate with energy quantization; Understand the method of obtaining time-independent Schrodinger equation and eigenfunctions, and quantized energies, interpretation of wavefunctions, and postulates and describe them, and apply to simple 1D potentials, barriers.
- Understand quantum mechanics of simple harmonic oscillators and vibrational levels of molecules.
- Understand angular momentum, commutation relations, eigenvalues and eigenfunctions; understand Spin, eigenvalues and spin states, addition of angular momentum and spin and spin-orbit coupling in the vector model, rotational levels of molecules.
- Understand the application of Schrodinger’s theory to Hydrogen atom and its spectrum at gross and fine levels, and spectroscopic notation.
Evaluation Pattern: As in the rules for Assessment Procedure (R.14)
Skills and Employability: The entire contents of this course, tutorials and assignments lays conceptual/theoretical foundation for application of laws of physics to problems of scientific interest and builds skills required for a career as an educator/academician in schools, colleges, universities and coaching centres, as a professional researcher in government/industrial research organizations, and as a communicator of science in general.