Publication Type : Journal Article
Publisher : Journal of Coordination Chemistry
Source : Journal of Coordination Chemistry, Volume 63, Number 8, p.1451-1461 (2010)
Url : http://dx.doi.org/10.1080/00958971003770405
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2010
Abstract : A series of new binucleating CoII, NiII, CuII, and ZnII complexes of bicompartmental ligands with SNO donors was prepared. The Schiff bases were obtained by the condensation of 4,6-diacetylresorcinol and mercapto-substituted 1,2,4-triazoles. The ligands and their complexes were characterized by elemental analysis, infrared, 1H-NMR, UV-Vis, FAB-mass, and ESR spectral studies, magnetic susceptibility, and conductivity measurements. All the complexes were monomeric and binuclear. NiII and CoII complexes were octahedral, whereas CuII and ZnII complexes were square planar and tetrahedral, respectively. The compounds are investigated for electrochemical activity
Cite this Research Publication : Dr. Naveen V. Kulkarni, M. P. Sathisha, Srinivasa Budagumpi, Gurunath S. Kurdekar, and Vidyanand K. Revankar, “Binuclear transition metal complexes of bicompartmental SNO donor ligands: synthesis, characterization, and electrochemistry”, Journal of Coordination Chemistry, vol. 63, pp. 1451-1461, 2010