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Publication Type : Journal Article
Publisher : Acta Crystallographica Section E: Structure Reports Online
Source : Acta Crystallographica Section E: Structure Reports Online, vol. 64, pp. m303-m304, 2008
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2008
Abstract : The asymmetric unit of the title compound, {[Cu(C4H2O4)(C3H10N2)(H2O)] ·H2O} n , consists of two CuII atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C3H10N2)(H2O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu - O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent CuII atoms in adjacent chains, forming a three-dimensional framework. One of the CuII atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O - H⋯O and N - H⋯O hydrogen bonds are observed in the crystal structure.
Cite this Research Publication :
Prof. M. Padmanabhan, J.C. Joseph, S. Olsson, and M. Bakir, “Catena-Poly[[[aqua(propane-1,3-diamine-κ2 N,N′)copper(II)]-μ-fumarato-κ2 O:O′] monohydrate]”, Acta Crystallographica Section E: Structure Reports Online, vol. 64, pp. m303-m304, 2008