Publication Type : Journal Article
Publisher : Taylor & Francis
Source : Designed Monomers and Polymers, 2003
Url : https://www.tandfonline.com/doi/abs/10.1163/156855503321127556
Campus : Amritapuri
School : School of Biotechnology
Verified : No
Year : 2003
Abstract : Polystyrene-supported β-diketone-linked palladium complexes on refluxing with olefins at 70°C in a methanol-water medium for 10 h afforded carbonyl compounds. The course of the reaction was influenced by the degree of cross-linking of the polymer matrix, the distance between the polymer matrix and the metal complex, and the structural environment of the ligand. The reaction is assumed to proceed through a hydroxy-palladation intermediate. A suitable mechanism is also suggested.
Cite this Research Publication : Vipin A. Nair, M. M. Suni and K. Sreekumar, "Catalytic studies on polymer supported metal complexes", Designed Monomers and Polymers 2003, 6, 81-89