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Lithium perchlorate-induced electrophilic activation: one-pot synthesis of 3-aryl-2-thioxotetra hydropyrimidin-4-one derivatives from aryl isothiocyanates

Publication Type : Journal Article

Publisher : Elsevier

Source : Tetrahedron Letters, 2010

Url : https://www.sciencedirect.com/science/article/pii/S0040403909023296?casa_token=E3q4YQ4H4P0AAAAA:eFOk3HNsglTt_rTDNXY3FFeHz8uSP812KXOmcDh_Oqkm64pwSsmbcHIxeYTiSz2516iFz8oNEac

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2010

Abstract : A novel methodology for the synthesis of N-substituted-3-aryl-2-thioxotetrahydropyrimidin-4(1H)-one derivatives had been developed by the condensation of aryl isothiocyanates with β-amino esters using lithium perchlorate as a catalyst and triethylamine as a base. This strategy not only overcomes the disadvantages of the reported methods but also provides high yield of the product in short span of time by an easily workable procedure.

Cite this Research Publication : Varun Kumar and Vipin A. Nair, "Lithium perchlorate-induced electrophilic activation: one-pot synthesis of 3-aryl-2-thioxotetra hydropyrimidin-4-one derivatives from aryl isothiocyanates", Tetrahedron Letters 2010, 51, 966-969.

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