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An efficient strategy for the synthesis of syn 1,3-diols via iterative acetate aldol reactions and synthesis of atorvastatin lactone

Publication Type : Journal Article

Publisher : Elsevier

Source : Tetrahedron Letters, 2015

Url : https://www.sciencedirect.com/science/article/pii/S0040403915012927?casa_token=ymQS5r-fu2sAAAAA:yqVsLfDfNDxsLxdd_LAVcAHyYcQknb7p74zi56NUNxtlk1ABwziyuXO1RcStCReXJhSrMHFT9ak

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2015

Abstract : An efficient strategy for the synthesis of syn 1,3-diol has been developed, employing an imidazolidinone based chiral auxiliary via stereoselective and sequential double acetate aldol reactions. The syn 1,3-diol subunit was modified to obtain the C-7 carboxylic acid side chain and further subjected to reaction with a suitable 1,4-diketone under Paal-Knorr conditions to obtain atorvastatin lactone.

Cite this Research Publication : Sandeep Goyal, Bhautikkumar Patel, Ratnesh Sharma, Mangilal Chouhan, Kapil Kumar, Mukesh Gangar and Vipin A. Nair, "An efficient strategy for the synthesis of syn 1,3-diols via iterative acetate aldol reactions and synthesis of atorvastatin lactone", Tetrahedron Letters 2015, 56, 5409-5412

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