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Synthesis and Crystal Structure of 1, 3-Dimesitylimidazolium 2, 4, 6-Triflurophenolate· 2, 4, 6-Triflurophenol

Publication Type : Journal Article

Publisher : Taylor & Francis Group

Source : Molecular Crystals and Liquid Crystals Volume 557 Issue 1 Pages 262-267, 2015

Url : https://www.tandfonline.com/doi/abs/10.1080/15421406.2011.644500

Campus : Coimbatore

School : School of Physical Sciences

Department : Department of Sciences

Year : 2015

Abstract : The basicity of 1,3-dimesitylimidazol-2-ylidene was verified by treating with two equivalent of 2,4,6-triflurophenol. The resulted compound 1,3-dimesitylimidazolium 2,4,6-triflurophenolate·2,4,6-triflurophenol (1) was crystallized in monoclinic centrosymmetric space group P21/c with unit cell parameters a = 7.9597(11) Å, b = 14.076(2) Å, c = 25.594(4) Å, and β = 93.042(3)°. The obtained solid state structure of 1,3-dimesitylimidazolium 2,4,6-triflurophenolate·2,4,6-triflurophenol shows different types of CH- - - F, CH- - - O interactions and were analyzed.

Cite this Research Publication : Elango Kandasamy, "Synthesis and Crystal Structure of 1, 3-Dimesitylimidazolium 2, 4, 6-Triflurophenolate· 2, 4, 6-Triflurophenol", Molecular Crystals and Liquid Crystals Volume 557 Issue 1 Pages 262-267, 2015

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