Unit 1
Atomic Physics: Dipole selection rules examples, Natural and Doppler Broadening, Spin-orbit coupling, Lamb shift and Rutherford experiment,
Course Name | Atomic and Molecular Spectroscopy |
Course Code | 22PHY512 |
Semester | 8 |
Credits | 4 |
Atomic Physics: Dipole selection rules examples, Natural and Doppler Broadening, Spin-orbit coupling, Lamb shift and Rutherford experiment,
Hyperfine structure: Hyperfine structure of lines, Normal and specific mass shifts, Anomalous Zeeman effect, Paschen-Back and Stark Effects, Quantum defect.
Molecular Physics: Rotational Spectra: Transition probabilities, selection rules. Rotational spectra of diatomic molecule- rigid and non-rigid rotator models. The Franck Condon principle. Dissociation energy. A brief discussion of Intensity alternation and missing lines in rotational spectra
Vibrational spectra: Vibrational spectra of a diatomic molecule – harmonic and anharmonic oscillator models. Normal modes of vibration and their distribution into symmetry species of the molecule, Overtone and Combination Bands, Vibrational Potentials, Infrared and Raman Selection rules. Vibration-Rotation Energy Levels and Spectra: Spectra of rotational vibrational levels, Rotational Raman and IR Spectra of linear molecules and Determination of their Geometry. Rotation-Vibration Band of a Diatomic Molecule and polyatomic molecules. Vibrational structure of electronic transition
Resonance Spectroscopy: ESR and NMR. Lande g factor, Spliting of degenerate states. Precession and spectra, selection rules, fine structure, Resonance spectra of some organic molecules.
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